n-pentane isomerization over Pt-Al promoted sulfated zirconia nanocatalyst
نویسندگان
چکیده
منابع مشابه
Rapid H2O2-promoted oxidation of anazolene sodium over the [BMIM]PF=/Pt/γ-Al2O3 nanocatalyst
Highly meso-porous Pt contained γ-Al2O3 nanostructure was prepared by a combined sol gel-pyrolysis method in the presence of polyvinylpyrrolidone and Pluronic p123 as surfactant. The surface of the prepared nanostructure was decorated with 1-Butyl-3-methylimidazolium hexafluorophosphate ([BMM]PF6) ionic liquid to enhance the sorption capacity and prevent the poisoning of the catalytic active si...
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The hydroisomerization of pure n-pentane over H-mordenite supported Pt-catalyst was investigated in a fixed bed reactor by changing reaction parameters such as temperature, pressure, and WHSV, as well as the H2/HC ratio. The maximum yield of isopentane over Pt/mordenite catalyst was achieved at 220 °C and a relatively low reaction pressure. To address the effect of feed composition on the catal...
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Catalytic performance and formation of carbonaceous deposits were studied simultaneously during alkane isomerization over sulfated zirconia in a fixed bed flow reactor with an optical window for in situ UV–vis diffuse reflectance spectroscopy. The reactions of n-butane (5 kPa) at 358 and 378 K and of n-pentane (0.25 kPa) at 298 and 308 K passed within 5 h or less through an induction period, a ...
متن کاملn-Butane Isomerization Catalyzed by Sulfated Zirconia Nanocrystals Supported on Silica or γ-Alumina
Supported sulfated zirconia catalysts with zirconia contents of 10, 20 and 50 wt% were prepared by impregnation of SiO2 and γ-Al2O3 supports with H2SO4/Zr(SO4)2 solutions followed by calcination at 923 K. The catalysts were characterized by X-ray diffraction, extended X-ray absorption fine structure measurements, thermal analysis, UV–vis spectroscopy, and electron microscopy. Tetragonal zirconi...
متن کاملPlatinum- and iron-doubly promoted tungstated zirconia catalyst for n-butane isomerization reaction
The catalysis of n-butane isomerization over iron-promoted tungstated zirconia (F1.2WZ) and platinum–iron-promoted tungstated zirconia (P/F1.2WZ) catalysts was studied and correlated to the catalyst characterization results. In the singly promoted F1.2WZ catalyst, we suggest that the iron species promotes the n-butane isomerization reaction through a redox effect. The formation of W–O–Fe linkag...
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ژورنال
عنوان ژورنال: Scientia Iranica
سال: 2017
ISSN: 2345-3605
DOI: 10.24200/sci.2017.4110